This was 5.5 percent higher than the state average of 41.1 percent. In 2020 the total municipality population reached 524.
83.6 percent of the population had at least a high school diploma or the equivalent.
Degree distribution in Orleans for 2020*
| Degree | Number of people | Percentage of population |
|---|---|---|
| No degree | 76 | 16.4 |
| Regular high school diploma | 61 | 13.1 |
| GED or alternative credential | 10 | 2.2 |
| Some college, less than 1 year | 34 | 7.3 |
| Some college, 1 or more years, no degree | 67 | 14.4 |
| Associate's degree | 28 | 6 |
| Bachelor's degree | 136 | 29.3 |
| Master's degree | 33 | 7.1 |
| Professional school degree | 16 | 3.4 |
| Doctorate degree | 3 | 0.6 |
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